I assume this is to little information to help me, if so feel free to ask any questions.
In the screen shot, I can not know what file manager that is, and that might be relevant.
Tip: Perhaps try a different file manager, for example "thunar", see if the same thing happens.
And I just noticed something odd,
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GIO_LAUNCHED_DESKTOP_FILE=/usr/share/applications/debian-uxterm.desktop
I tried using thunar, and the open with terminal worked fine, my default being then when I tried using
"uxterm", it would not, just like you say, it does nothing. I happen to have uxterm installed because I wanted to try it, but did not like it, so try using xterm as default, or some other terminal.
Of course check .xsession-errors like H-O-A-S says as well...
Eg:
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.xsession-errors
xterm: No absolute path found for shell: /home/cuckoo/ISOimages
Failed to connect to session manager: Failed to connect to the session manager: SESSION_MANAGER environment variable not defined
PCRE2 library was built without JIT support
This is when I tried using "uxterm", I don't know why it says "xterm",... But the message is clear, I need to configure / define my SESSION_MANAGER environment (I think)
Note , I am not on Debian, but for a example it is good, yours may appear different