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Are we dealing with Debian here or Knoppix? Dozens of distros are "based" on Debian but this is Debian User Forums for (just) Debian. We cannot deal with the dozens here.
It's sort of a bug in Synaptic I've encountered. It happens when you have Synaptic set to prefer packages from a specific distro, wheezy in your case, and then disable any repos that provide that source, and then reload. Synaptic will then not start.
I've fixed it by restoring that repo by manually editing the sources.list file, then apt-get update. Then Synaptic can start, and then the preferences for the distro can be changed to what you want for the future, followed by disabling the old repo again.
I'm sure someone will chime in a with a config file edit that will fix it in one step, too...
knoppix@Microknoppix:~$ su -c "sed -i 's/DefaultDistro \".*\"/DefaultDistro \"\"/' /root/.synaptic/synaptic.conf"
sed: can't read /root/.synaptic/synaptic.conf: No such file or directory
Anyway, did you try my solution of restoring the wheezy repository just long enough to do an "apt-get update", then setting Synaptic to prefer something other than Wheezy?